I'm certainly open to the idea that you can hear a change and I'm relieved to see you have described it as slight, that's a refreshingly honest appraisal of this phenomenon. Most people wax lyrical about the night and day difference a valve change makes. If it does then they had VERY badly worn out valves before that which are way way off spec. I absolutely agree that any changes you get rolling are dwarfed by speaker changes which produce genuine big differences in tonal characteristics. The only thing I take issue with is that these audible differences are not caused by valves from different manufacturers having different frequency responses, they simply do not. They all produce a flat response from DC to above audio frequencies. It is the interplay of different genuine differences in valves' characteristics which can cause a degree of tonal variation in the overall circuit. That should be taken on board and the whole "frequency response" myth put to bed in order to stop the snake oil salesmen doing their job, just as the guys at Amplified Parts are doing. Their individual "appraisal" charts for each graph are split into a range of 0-10. If you look at their own frequency plots which I posted and read off the figures you will find that that 0-10 represents a real range of 2.8dB - maximum. In the "red/grey/yellow" bargraphs of the valves tested, they show that the maximum difference for any valve between its Bass Mid and Treble is 2 steps on their scale. That represents less than 0.6dB - maximum for any valve. That is inaudible to all but a member of the Marvel Superheroes in any real setting.
Sadly, the whole "decide by listening tests" idea is fatally flawed for the home user right from the start. The ear/brain simply cannot hold onto any accurate tonal information for longer than a few seconds so the only way to compare with any hope of accuracy is an instantaneous swap between valves in what must be the exact same circuit. To listen to one valve then switch off, swap the valve out and switch on again, then wait for the new valve to warm up is far too long for the brain to retain a clear accurate memory of what it has already heard. That is when the listener's own expectations come into play in what they hear. This is a well documented phenomenon and is taken into account in genuine tests. I have in the past been a part of double blind comparisons where people listen to two items swapped at random repeatedly and say which they think they were listening to. They always show that, while people think they can identify and describe differences when they know which they are listening to, as soon as they are not aware of which is which they still think they can hear differences but, strangely, their guesses as to which is which now drop to 50% right and 50% wrong.
It takes highish repetitions to generate the number of results required to accurately analyse this statistically of course, but the results do show that there is only an absolutely statistically insignificant chance that they really can identify differences under these conditions. As an aside, this test absolutely destroys the "super tone capacitor" idea for your tone cap in your guitar!!! With just a simple switch for the tester to swap between the two in the player's guitar cavity and a coin to flip to either change or not change, guitarists have no idea when there is an Orange Drop or a "nasty" ceramic in there. Gibson used to use the dreaded ceramics on a huge range of their guitars and everyone loved them - when they didn't know they were "bad things". Then gradually the internet started reporting that techy guru types had found "unsuitable capacitors" in them and suddenly everyone could hear that their guitars now sounded - well - crap! They still couldn't identify any differences in a blind listening test though. That's the level some of these issues descend to. If you question and test the King always seems to end up having no clothes!
I have always thought that there may be a semantic difference in what people are meaning by "tone" to how I use it. Tone to me is a frequency based characteristic. I separate it from aspects like the character of overdrive and distortion which are much more relevant to our playing. Those are not tonal aspects which you measure with frequency response plots. You yourself mentioned FFTs and that is a totally different ballgame to simple frequency plots, much more revealing and relevant to the real sound when playing. You are then looking at the ever changing production of a huge range of harmonics which cannot be described by simply looking at the frequency response which only applies to steady state clean signals.
And you are of course right, the plot didn't go past 10kHz, but it isn't really relevant to us. That is because the guitar only produces its relevant output up to about 6kHz or so before it has tailed off drastically. Pickups, as coils with a huge number of turns and seriously magnetic cores, have very high inductance which is not at all good for high end responses. And don't forget guitar speakers are also very limited in bandwidth too, by design. For example, the Vintage 30 which is usually thought of as a pretty toppy sharp speaker begins a very steep drop at 4kHz and is 25-30dB down at 10kHz. Most other types are at least that much down with some more mellow types even more. That last octave up to 20kHz is a must for hifi but an absolute no-no for guitar to get the sound we expect nowadays. Just as well for us they limit as they do as the tone they do produce is just right for rocking at that bandwidth.
Here is a little tickler for you. Look at this old thread from our own forum:
Tube Swapping - for something outrageous Look for post #122 by Voodoo Jeff and read down a few responses. He talks about his set of Wathen CryoTone valves, (you can find them online under Wathen Audio). The 12AX7s currently start at $93!!! while the EL84s are $95 a piece (and that is - each). Jeff still describes the difference between these and his usual plain old JJs as "subtle at best" and he is a professional musician with demanding tastes. It makes you think.